Correction to Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms
نویسندگان
چکیده
Experimental Details S3 General Considerations S3 Synthesis of 2 S3 Synthesis of 3 S4 Synthesis of 4 S4 Synthesis of 5 S5 Synthesis of 6 S6 Synthesis of 6-HD S6 Synthesis of 7 S6 Synthesis of 8 S7 Reaction of 8 with D2 S7 Reactivity with AB Analogs S7 Time Resolved AB Dehydrogenation Experiments S8 NH2BH2 Trapping Experiments S8 Eudiometric Measurement Details S8 Figure S1—Eudiometer Diagram S9 Reaction Kinetics Measurements S10
منابع مشابه
Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms
Though numerous catalysts for the dehydrogenation of ammonia borane (AB) are known, those that release >2 equiv of H2 are uncommon. Herein, we report the synthesis of Mo complexes supported by a para-terphenyl diphosphine ligand, 1, displaying metal-arene interactions. Both a Mo(0) N2 complex, 5, and a Mo(II) bis(acetonitrile) complex, 4, exhibit high levels of AB dehydrogenation, releasing ove...
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